Recent Advances in Intermolecular Hydroacylation of Alkenes with Aldehydes through Rhodium Catalysis

2018/05/23 by Guozhu Zhang, Rui Guo
Chemistry · #Asymmetric Hydrogenation and Catalysis #Catalytic Cross-Coupling Reactions #Catalytic C–H Functionalization Methods

paper · doi:10.1055/s-0037-1610141

openalex publication_date 2018/05/23 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/30

Abstract

The rhodium-catalyzed intermolecular hydroacylation of alkenes with aldehydes is an atom-economical method for the synthesis of ketones. Here, we give a brief review on its development and we highlight recent advances in chelating strategies for the stabilization of acyl rhodium species by coordinative saturation.

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