2001/01/29 by Yurii M. Loskutov, Loskutov, Yurii M.
Chemistry · Engineering · Physics and Astronomy · #Chemical Thermodynamics and Molecular Structure #FOS: Physical sciences #Field-Flow Fractionation Techniques #Phase Equilibria and Thermodynamics #Statistical Mechanics (cond-mat.stat-mech) #cond-mat.stat-mech
paper · pdf · doi:10.48550/arxiv.cond-mat/0101432
LaTeX2e, 19 pages with 2 Postscript figures
arxiv created 2001/01/29 · openalex publication_date 2001/01/29 · arxiv updated 2009/11/30 · openalex created_date 2016/06/24 · openalex updated_date 2026/07/28
It is shown that the partial temperatures of a homogeneous multicomponent gas mixture in the thermodynamical equilibrium cannot be equal to each other. New general solutions for equilibrium distribution functions of the multicomponent mixture are found. Parameters (including partial temperatures) involved in these solutions are determined by means of physical conditions which follow from a notion of the stable thermodynamical equilibrium. The found relations of the partial temperatures to the mean mixture temperature are dependent on the molecular weights and concentrations of the components. Some possible consequences of the developed approach are discussed.