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Ge epitaxy at ultra-low growth temperatures enabled by a pristine growth environment

2024/10/04 by Christoph Wilflingseder, Johannes Aberl, Wilflingseder, Christoph +25 · 1 citation
Engineering · Materials Science · #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Mesoscale and Nanoscale Physics (cond-mat.mes-hall) #Photonic and Optical Devices #Semiconductor Lasers and Optical Devices #Silicon Nanostructures and Photoluminescence

paper · pdf · doi:10.48550/arxiv.2410.03295

openalex publication_date 2024/10/04 · openalex created_date 2024/10/31 · openalex updated_date 2026/07/28

Abstract

Germanium (Ge), the next-in-line group-IV material, bears great potential to add functionality and performance to next-generation nanoelectronics and solid-state quantum transport based on silicon (Si) technology. Here, we investigate the direct epitaxial growth of two-dimensional high-quality crystalline Ge layers on Si deposited at ultra-low growth temperatures (TGe = 100C-350C) and pristine growth pressures (\lesssim 10-10 mbar). First, we show that TGe does not degrade the crystal quality of homoepitaxial Ge/Ge(001) by comparing the point defect density using positron annihilation lifetime spectroscopy. Subsequently, we present a systematic investigation of the Ge/Si(001) heteroepitaxy, varying the Ge coverage (θGe, 1, 2, 4, 8, 12, and 16 nm) and TGe (100C to 300C, in increments of 50C) to assess the influence of these parameters on the layer's structural quality. Atomic force microscopy revealed a rippled surface topography with superimposed grainy features and the absence of three-dimensional structures, such as quantum dots. Transmission electron microscopy unveiled pseudomorphic, grains of highly crystalline growth separated by defective domains. Thanks to nanobeam scanning x-ray diffraction measurements, we were able to evidence the lattice strain fluctuations due to the ripple-like structure of the layers. We conclude that the heteroepitaxial strain contributes to the formation of the ripples, which originate from the kinetic limitations of the ultra-low temperatures.

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