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Abnormal Magnetic Behaviors in Unique Square alpha-MnO2 Nanotubes

2012/07/13 by R. Zeng, Zeng, R., J. Q. Wang +11
Physics and Astronomy · #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.1207.3350

23 Pgs, 10 Figs

arxiv created 2012/07/13 · arxiv updated 2012/07/17

Abstract

Systematic magnetic measurements have been performed in uniqueα- MnO2 square nanotubes synthesized by a facile hydrothermal method with microwave-assisted procedures. Unusual magnetic phenomena (abnormal magnetization verse temperature (M - T) behaviour, large and abnormal magnetization hysteresis loop horizontal shift (HHS) verse cooling field (HFC) behaviours (HHS - HFC) has been observed in these square nanotubes. These suggest the observation of large unfrozen orbital moment which also is the micro -original of observed large and abnormal horizontal shift (HHS). The findings demonstrated that engineering layered structures in nanoscale would create many unique nanostructures and unusual physicochemical behaviours.

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