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Architected Various MnO6 Octahedral Layers MnO2 Nanostructures

2012/07/13 by R. Zeng, Renfen Zeng, J. Q. Wang +15
Chemistry · Materials Science · Physics and Astronomy · #FOS: Physical sciences #Magnetic Properties and Synthesis of Ferrites #Mesoscale and Nanoscale Physics (cond-mat.mes-hall) #Multiferroics and related materials #Nanomaterials for catalytic reactions #cond-mat.mes-hall

paper · pdf · doi:10.48550/arxiv.1207.3222

15 Pgs, 7 Figs

arxiv created 2012/07/13 · openalex publication_date 2012/07/13 · arxiv updated 2012/07/16 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

A series of MnO2 unique nanostructures were synthesized by a facile hydrothermal method with microwave-assisted procedures. A novel nanostructure formation mechanism has been proposed, that MnO6 octahedral nuclei and molecular layers can be rearranged into different nanostructured morphologies by restacking and splitting, and then clasping, which is associated with tunnel structure phase transformation. Systematic macrostructure observations and magnetic property measurements have been conducted on these nanostructures, which demonstrate that engineering layered structures has the potential to create many unique nanostructures and unusual physicochemical behaviours.

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