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Synthesis of Cobalt Grown from Co-S Eutectic in High Magnetic Fields

2025/04/01 by Flynn, Steven, Benyacko, Caeli L., Mihalik, Matúš +8 · 1 citation
#FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci)

paper · doi:10.48550/arxiv.2504.00788

Abstract

Samples of Co were grown directly in the ferromagnetic state under equilibrium conditions using a cobalt sulfide flux. Magnetic fields up to 9 T were applied during growth, and isolated Co products exhibit progressively elongated morphologies, from cubes to rectangular rods to needle-like tendrils with poorly-defined facets. The degree of elongation of the major axis was found to correlate with magnetic field direction, strength, and gradient. Two-dimensional X-ray diffraction data indicate some level of polycrystalline-like samples, and quantitative analyses (Le Bail and Rietveld) of the one-dimensional data confirm the presence of hcp and fcc phases. The magnetic responses indicate a partial alignment of the magnetic easy-axis of the hcp phase along the magnetic field present during growth.

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