2004/10/28 by Kazunari Yamaura, K. Yamaura, Q. Huang +21
Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Crystal Structures and Properties #FOS: Physical sciences #Magnetism in coordination complexes #Strongly Correlated Electrons (cond-mat.str-el) #Superconductivity (cond-mat.supr-con) #cond-mat.str-el #cond-mat.supr-con
paper · pdf · doi:10.48550/arxiv.cond-mat/0410742
Accepted for publication in Chem. Mater
arxiv created 2004/10/28 · openalex publication_date 2004/10/28 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01
The sodium rhodate NaRh2O4 was synthesized for the first time and characterized by neutron and x-ray diffraction studies, measurements of magnetic susceptibility, specific heat, electrical resistivity, and the Seebeck coefficient. NaRh2O4 crystallizes in the CaFe2O4-type structure, which is comprised of a characteristic RhO6 octahedra network. The compound is metallic in nature, probably reflecting the 1 to 1 mixed valence character of Rh(III) and Rh(IV) in the network. For further studies of the compound, the Rh valence was varied significantly by means of an aliovalent substitution: the full range solid solution between NaRh2O4 and CaRh2O4 was achieved and characterized as well. The metallic state was dramatically altered, and a peculiar magnetism developed in the low Na concentration range.