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Solvent-antisolvent interactions in metal halide perovskites

2024/04/17 by José Roberto Bautista‐Quijano, Oscar Telschow, Bautista-Quijano, Jose Roberto +5 · 1 citation
Engineering · Materials Science · #FOS: Physical sciences #Materials Science (cond-mat.mtrl-sci) #Perovskite Materials and Applications #Solid-state spectroscopy and crystallography

paper · pdf · doi:10.48550/arxiv.2404.11637

openalex publication_date 2024/04/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/04

Abstract

The fabrication of metal halide perovskite films using the solvent-engineering method is increasingly common. In this method, the crystallisation of the perovskite layer is triggered by the application of an antisolvent during the spin-coating of a perovskite precursor solution. Herein, we introduce the current state of understanding of the processes involved in the crystallisation of perovskite layers formed by solvent engineering, focusing in particular on the role of antisolvent properties and solvent-antisolvent interactions. By considering the impact of the Hansen solubility parameters, we propose guidelines for selecting the appropriate antisolvent and outline open questions and future research directions for the fabrication of perovskite films by this method.

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