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In-operando quantitation of Li concentration for commercial Li-ion rechargeable battery using high-energy X-ray Compton scattering

2017/07/12 by Kosuke Suzuki, Suzuki, Kosuke, Ayahito Suzuki +17
Materials Science · Physics and Astronomy · #Applied Physics (physics.app-ph) #Electron and X-Ray Spectroscopy Techniques #FOS: Physical sciences #Graphite, nuclear technology, radiation studies #X-ray Spectroscopy and Fluorescence Analysis #physics.app-ph

paper · pdf · doi:10.48550/arxiv.1707.03727

12 pages, 8 figures

arxiv created 2017/07/12 · openalex publication_date 2017/07/12 · arxiv updated 2017/07/13 · openalex created_date 2017/07/21 · openalex updated_date 2026/07/28

Abstract

Compton scattering is one of the promising probe to quantitate of the Li under in-operando condition, since high-energy X-rays which have high penetration power into the materials are used as incident beam and Compton scattered energy spectrum have specific line-shape by the elements. We develop in-operando quantitation method of Li composition in the electrodes by using line-shape (Sparameter) analysis of Compton scattered energy spectrum. In this study, we apply S-parameter analysis to commercial coin cell Li-ion rechargeable battery and obtain the variation of S-parameters during charge/discharge cycle at positive and negative electrodes. By using calibration curves for Li composition in the electrodes, we determine the change of Li composition of positive and negative electrodes through S-parameters, simultaneously.

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