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Enhancement in thermoelectric properties of FeSb2 by Sb site deficiency

2015/04/30 by Anup V. Sanchela, Sanchela, Anup V., Ajay D. Thakur +3
Materials Science · Physics and Astronomy · #Advanced Thermoelectric Materials and Devices #FOS: Physical sciences #Heusler alloys: electronic and magnetic properties #Materials Science (cond-mat.mtrl-sci) #Surface and Thin Film Phenomena #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.1504.08174

arxiv created 2015/04/30 · openalex publication_date 2015/04/30 · arxiv updated 2015/05/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We report a strategy based on introduction of point defects for improving the thermoelectric properties of FeSb2, a promising candidate for low temperature applications. Introduction of Sb deficiency to the tune of 20% leads to enhancement in the values of electrical conductivity (σ) and Seebeck coefficient (S) accompanied with a concomitant suppression in lattice thermal conductivity (\kappalat) values in samples prepared using conventional solid state reaction route. These observations in polycrystalline FeSb2-x provides ample motivation for a dedicated exploration of thermoelectric behavior of the corresponding single crystalline as well as hot-pressed polycrystalline counterparts.

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