2015/09/24 by Glauco Meireles Mascarenhas Morandi Lustosa, Glauco M. M. M. Lustosa, João Paulo de Campos da Costa +6
Chemistry · Engineering · Materials Science · #Analytical Chemistry (journal) #Chemistry #Composite material #Dielectric properties of ceramics #Diffusion #Diffusion barrier #Electrical engineering #Electrical resistivity and conductivity #Gas Sensing Nanomaterials and Sensors #Grain boundary #Grain boundary diffusion coefficient #Grain size #Layer (electronics) #Materials science #Metallurgy #Microstructure #Mineralogy #Thermodynamics #Varistor #Voltage #ZnO doping and properties
paper · doi:10.1111/jace.13924
openalex publication_date 2015/09/24 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/26
The effect of Cr 3+ on the electrical properties of SnO 2 ‐based films deposited by electrophoresis on Si/Pt substrate was considered. The films were sintered in a microwave oven at 1000°C/40 min and then the surface was modified with deposition of Cr 3+ ions by electrophoresis. The diffusion of Cr 3+ contributes to the modification of the potential barrier formed on the grain boundary improving the electrical properties due to electron acceptor species adsorption on the grain boundary. The influence on the properties of grain boundary was verified by I versus V characterization in as a function of temperature. The films showed nonlinear coefficient over 9, potential barrier height over 0.5 eV and resistivity greater than 10 7 Ω·cm. 4 samples were prepared at same conditions and presented similar electrical behavior, showing the efficiency of technique on reproducibility to varistor properties control. Thereby the nonlinear coefficient increases while decreasing the conductivity of the system is noticed.