1987/07/01 by R. H. Lamoreaux, D. L. Hildenbrand, L. Brewer +1 · 4 citations
Earth and Planetary Sciences · Materials Science · Chemistry · #nanoparticles nucleation surface interactions #Thermal and Kinetic Analysis #Chemical Thermodynamics and Molecular Structure
paper · doi:10.1063/1.555799
In order to assess the high-temperature vaporization behavior and equilibrium gas phase compositions over the condensed oxides of Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Zn, Cd, and Hg, the relevant thermodynamic and molecular constant data have been compiled and critically evaluated. Selected values of the Gibbs energy functions of condensed and vapor phases are given in the form of equations valid over wide temperature ranges, along with the standard entropies and enthalpies of formation. These data were used to generate plots of equilibrium partial pressures of vapor species as functions of temperature for representative environmental conditions ranging from reducing to oxidizing. The calculated partial pressures and compositions agree, for the most part, with experimental results obtained under comparable conditions. Maximum vaporization rates have been calculated using the Hertz–Knudsen equation. Literature references are given.