Three-Component Carboboration of Alkenes under Copper Catalysis

2014/05/14 by Hiroto Yoshida, Ikuo Kageyuki, Ken Takaki
Chemistry · Medicine · #Organoboron and organosilicon chemistry #Boron Compounds in Chemistry #Catalytic Cross-Coupling Reactions

paper · doi:10.1055/s-0033-1341267

Abstract

Three-component carboboration of alkenes takes place efficiently by the reaction with a diboron compound and carbon electrophiles with the aid of a copper–NHC catalyst. The carboboration afforded diverse multisubstituted borylalkanes via the regio­selective formation of carbon–boron and carbon–carbon bonds.

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