[2.2]Paracyclophane Derivatives: Synthesis and Application in Catalysis

2011/10/19 by Jan Paradies · 4 citations
Chemistry · Engineering · #Asymmetric Hydrogenation and Catalysis #Surface Chemistry and Catalysis #Synthesis and Properties of Aromatic Compounds

paper · doi:10.1055/s-0031-1289296

Abstract

Advances in the field of [2.2]paracyclophane chemistry are reviewed including syntheses, resolution of enantiomers and application in organic synthesis. Transition-metal catalyzed as well as organocatalytic transformations are presented focusing on the development of [2.2]paracyclophane derived ligands and catalysts.

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• Mixed Amide Paracyclophane Assemblies Emulating Supramolecular Copolymers
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• Enantiopure planar chiral [2.2]paracyclophanes: Synthesis and applications in asymmetric organocatalysis
• An Asymmetric Variant of the Bischler–Möhlau Indole Synthesis*

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