New Synthesis of α-Nitroso Esters and Oximes of α-Keto Esters

1988/01/01 by Syed Masarrat Ali, Yoshihiko Matsuda, Shigeo Tanimoto
Chemistry · #Synthesis of heterocyclic compounds #Organic Chemistry Synthesis Methods #Synthesis and Reactions of Organic Compounds

paper · doi:10.1055/s-1988-27715

Abstract

Ketene O-alkyl O′-silyl acetals on reaction with nitric oxide or isomayl nitrite in the presence of titanium(IV) chloride provide either one of α-nitroso esters and oximes of α-keto esters.

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