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Nonlinear Screening and Effective Interactions in Charged Colloids

2001/10/04 by A. R. Denton, Denton, A. R.
Physics and Astronomy · #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #Statistical Mechanics (cond-mat.stat-mech) #cond-mat.soft #cond-mat.stat-mech

paper · pdf · doi:10.48550/arxiv.cond-mat/0110096

4 pages, 4 figures

arxiv created 2001/10/04 · arxiv updated 2009/11/30

Abstract

Influences of nonlinear screening on effective interactions between spherical macroions in charged colloids are described via response theory. Nonlinear screening, in addition to generating effective many-body interactions, is shown to entail essential corrections to the pair potential and one-body volume energy. Numerical results demonstrate that nonlinear effects can substantially modify effective interactions and thermodynamics of aqueous, low-salt suspensions of highly-charged macroions.

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