2004/03/08 by H. W. Zandbergen, Zandbergen, H. W., M. L. Foo +7
Physics and Astronomy · #FOS: Physical sciences #Superconductivity (cond-mat.supr-con) #cond-mat.supr-con
paper · pdf · doi:10.48550/arxiv.cond-mat/0403206
16 pages,13 figures
arxiv created 2004/03/08 · arxiv updated 2009/12/01
The layered sodium cobalt oxide NaxCoO2 is studied by electron diffraction for a wide range of sodium contents, 0.15<x<0.75. An extensive series of ordered Na ion-Na vacancy superlattices is found beyond the simple hexagonal average structure. The most strongly developed superlattice is found for the composition Na0.5CoO2, which displays Co3+/Co4+ charge ordering at low temperatures. The structural principle for some of the observed ordering schemes, particularly near x=0.5, is, surprisingly, the presence of lines of Na ions and vacancies rather than simply maximized Na-Na separations.