2018/10/15 by Eugene А. Eliseev, Eliseev, Eugene A., Anna N. Morozovska +5 · 2 citations
Engineering · Materials Science · #Acoustic Wave Resonator Technologies #FOS: Physical sciences #Ferroelectric and Piezoelectric Materials #Materials Science (cond-mat.mtrl-sci) #Multiferroics and related materials #Nonlocal and gradient elasticity in micro/nano structures
paper · pdf · doi:10.48550/arxiv.1810.06668
openalex publication_date 2018/10/15 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28
Using Landau-Ginzburg-Devonshire approach, we predict the intrinsic instability of the ferroelectric-ferroelastic domain walls in the multiferroic BiFeO3 emerging from the interplay between the gradient terms of the antiferrodistortive and ferroelectric order parameters at the walls. These instabilities are the interface analogue of the structural instabilities in the vicinity of phase coexistence in the bulk; and so they do not steam from incomplete polarization screening in thin films or its spatial confinement, electrostrictive or flexoelectric coupling. The effect of BiFeO3 material parameters on the 71 degree, 109 degree, and 180 degree walls is explored, and it is shown that the meandering instability appears at 109 degree, and 180 degree walls for small gradient energies, and the walls become straight and broaden for higher gradients. In contrast to the 180 degree and 109 degree domain walls, uncharged 71 degree walls are always straight, and their width increases with increasing the tilt gradient coefficient. The wall instability and associated intrinsic meandering provide a new insight into the behavior of morphotropic and relaxor materials, wall pinning, and mechanisms of interactions between order parameter fields and local microstructure.