Definition of the pnictogen bond (IUPAC Recommendations 2023)

2024/01/01 by Giuseppe Resnati, David L. Bryce, Gautam R. Desiraju +9 · 9 citations
Chemistry · #Crystallography and molecular interactions #Chemical Thermodynamics and Molecular Structure #Radioactive element chemistry and processing

paper · pdf · doi:10.1515/pac-2020-1002

Abstract

Abstract This recommendation proposes a definition for the term “pnictogen bond”; the term pnictogen bond designates a subset of the attractive interactions between an electrophilic region on a pnictogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity.

Citations

• 2018 Table of static dipole polarizabilities of the neutral elements in the periodic table

Cited by

• 77Se Solid-State NMR Investigation of Selenium Chemical Shift Tensors of Chalcogen Bonds in Selenadiazole Cocrystals
• Gold(I) organometallic supramolecular assemblies. Luminescence and applications
• From fluorine chemistry to noncovalent interactions: celebrating Prof. Giuseppe Resnati
• Cocrystallisation with carbon
• Halogens as noncovalent chemical chameleons: Electrophilic-nucleophilic dualism enabling multicenter halogen bond-based assemblies
• Understanding Non-Covalent Interactions in Diphenyldiselenide and Diphenylselenide Cocrystals Using a Combined 77Se Magic-Angle Spinning Solid-State NMR and Quantum Chemical Analysis Approach
• Blue-Shifting Hydridic Hydrogen Bonds in Complexes of (Me 3 Si) 3 SiH
• Is Cobalt Joining the σ-/π-Hole Crown? Exploring Noncovalent Interactions in Cobalamin
• Rotational Adaptability Offsets Geometric Mismatch and Preserves Directional Halogen Bonding in Self-Complementary 2-Iodooxazole Assemblies

Related

• Definition of the chalcogen bond (IUPAC Recommendations 2019)
• Definition of the halogen bond (IUPAC Recommendations 2013)
• Definition of the hydrogen bond (IUPAC Recommendations 2011)
• Not Only Hydrogen Bonds: Other Noncovalent Interactions
• When a covalent bond is broken?