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Crystal Structure and Cation Distribution of the X-type Hexaferrite Sr2Co2Fe28O46

2020/02/07 by Mai Komabuchi, Daisuke Urushihara, Toru Asaka +4
Materials Science · Physics and Astronomy · #Magnetic Properties and Synthesis of Ferrites #Multiferroics and related materials #Advanced Condensed Matter Physics

paper · doi:10.7566/jpsj.89.034601

Abstract

The crystal structure of an X-type hexaferrite Sr2Co2Fe28O46 was investigated by the x-ray and neutron diffraction methods for a single crystal. Sr2Co2Fe28O46 has the crystal structure described as a space group R\(3\)m (Z = 3) and its lattice constants are a = 5.9165(2) Å and c = 84.1395(33) Å at 843 K. Co ions are almost localized in the octahedral site (9d) in the middle of S*S* blocks. In addition, the adjacent octahedral and tetrahedral sites to 9d site contain the significant number of Co2+.

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