2023/10/13 by Urai, M., Miyagawa, K., Torunova, S. A. +3
#FOS: Physical sciences #Strongly Correlated Electrons (cond-mat.str-el)
paper · doi:10.48550/arxiv.2310.08963
We investigated the local magnetism of the organic conductor, κ-(ET)2Hg(SCN)2Cl, with a quasi-triangular lattice of weakly dimerized molecules through 13C NMR spectroscopy. The NMR spectra and nuclear relaxation show that charge disproportionation occurs, associated with the metal-insulator transition at 31 K. The relaxation rate indicates that the paramagnetic spins in the insulating phase undergo a transition into a spin-singlet ground state with the emergence of orphan spins, a possible valence-bond-glass state. The present results are in high contrast to the spin-cluster paramagnetism of the electric dipole-liquid candidate, κ--(ET)2Hg(SCN)2Br, having nearly identical material parameters. This fact indicates that these two systems are on the verge between distinct phases in both charge and spin degrees of freedom; a spin-singlet charge-ordered state versus a spin-active Mott insulating state, competing with each other on a triangular lattice of dimerized sites.