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Reexamination of Tolman's law and the Gibbs adsorption equation for curved interfaces

2017/03/25 by Martin Horsch, Martin Thomas Horsch, Horsch, Martin Thomas +17
Earth and Planetary Sciences · Engineering · Physics and Astronomy · #Atmospheric and Oceanic Physics (physics.ao-ph) #Atomic and Molecular Clusters (physics.atm-clus) #Chemical Physics (physics.chem-ph) #FOS: Physical sciences #Mesoscale and Nanoscale Physics (cond-mat.mes-hall) #Phase Equilibria and Thermodynamics #Soft Condensed Matter (cond-mat.soft) #Theoretical and Computational Physics #cond-mat.mes-hall #cond-mat.soft #nanoparticles nucleation surface interactions #physics.ao-ph #physics.atm-clus #physics.chem-ph

paper · pdf · doi:10.48550/arxiv.1703.08719

Manuscript arXiv:1703.08719 [cond-mat.soft] contains claims that were shown to be incorrect; the manuscript and the claims are retracted

openalex publication_date 2017/03/25 · arxiv created 2019/07/03 · arxiv updated 2019/07/04 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

In manuscript arXiv:1703.08719 [cond-mat.soft], it was claimed that the well-known deduction of Tolman's law is not rigorous, since Tolman's argument implies that two different definitions of the surface tension, called γ and γ in the manuscript, coincide. This claim is retracted as it can be shown by free-energy minimization that γ= γ indeed holds for the Laplace radius. Joachim Groß, Philipp Rehner, Carlos Vega, Øivind Wilhelmsen, and the anonymous reviewers of The Journal of Chemical Physics contributed to finding the mistake in the manuscript.

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