2023/02/10 by A. Ślebarski, Ślebarski, A., J. Spałek +3
Physics and Astronomy · #Advanced Chemical Physics Studies #FOS: Physical sciences #Rare-earth and actinide compounds #Strongly Correlated Electrons (cond-mat.str-el) #Topological Materials and Phenomena
paper · pdf · doi:10.48550/arxiv.2302.05194
openalex publication_date 2023/02/10 · openalex created_date 2023/02/14 · openalex updated_date 2026/07/28
It follows from our analysis of CeRhSb that the formation of Kondo insulator state due to the presence of the collective spin singlet state is strongly reduced by its doping with various dopants when their amount exceeds 8--10%, regardless of whether they are substituted for Ce, Rh or Sb. A wide variety of experimental results (electrical resistivity ρ, magnetic susceptibility χ, specific heat C, x-ray photoelectron spectroscopy) and theoretical investigations have convincingly demonstrated the proposed earlier scaling law χ×ρ=const. in the Kondo insulator regime, which is universal for all known Kondo insulators. We also analyze the properties of the Griffiths--phase for CeRhSb when Pd substitutes Rh, or Sb is fractionally replaced by Te and Sn, whereas doping of Ce with La leads to the formation of magnetic cluster structure as a result of the Kondo hole effect. Magnetoresistance of CeRhSb and CeRhSb0.98Te0.02 as a function of the field B shows a -B2 behavior, which provides evidence for the topologically nontrivial nature of these compounds, as was previously predicted theoretically for CeRhSb on the basis on the band structure calculations.