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First principle based phase stability in PMN-xPT

2009/11/27 by M. Sepliarsky, Sepliarsky, M., R. E. Cohen +1
Engineering · Physics and Astronomy · #Acoustic Wave Resonator Technologies #Advanced MEMS and NEMS Technologies #FOS: Physical sciences #Magnetic confinement fusion research #Materials Science (cond-mat.mtrl-sci) #cond-mat.mtrl-sci

paper · pdf · doi:10.48550/arxiv.0911.5306

27 pages including 10 figures

arxiv created 2009/11/27 · openalex publication_date 2009/11/27 · arxiv updated 2009/12/08 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

We have applied a shell model potential developed by fitting first principle results to describe the behavior of the relaxor-ferroelectric PMN-xPT as function of concentration. The solid solution exhibits three regions with different characteristics according to Ti content in agreement with the experiments. At low Ti the polar and structural disorder dominates, and the symmetry is rhombohedral. The intermediate region is ferroelectric with easy rotation of the polarization direction, and the symmetry appears orthorhombic. Finally, in the high Ti content region, the solid solution adopts a ferroelectric behavior similar to PT, with tetragonal symmetry.

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