The Reasons of Line Broadening of Lattice Oscillations in Spectrum Small Frequencies of P-Chloronitrobenzene

2006/02/26 by M. A. Korshunov, Korshunov, M. A.
Chemistry · Physics and Astronomy · #Analytical Chemistry and Chromatography #Chemical Thermodynamics and Molecular Structure #FOS: Physical sciences #Molecular Spectroscopy and Structure #Optics (physics.optics) #physics.optics

paper · pdf · doi:10.48550/arxiv.physics/0602183

4 pages, PDF PACS: 78.30. E; 61.72. J; 61.66. H; 78.30. J

arxiv created 2006/02/26 · openalex publication_date 2006/02/26 · arxiv updated 2009/12/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/28

Abstract

Raman spectroscopies are carried out by the Method polarizable examinations of the lattice oscillations of p-chloronitrobenzene at temperature 293 K. The led matching of spectrums of p-chloronitrobenzene with p-bromochlorobenzene and p-dibromobenzene has shown that the significant line broadening in p-chloronitrobenzene is caused not only clutter in allocation of molecules concerning parasubstitution benzol. It is necessary to consider also and clutter in rotational displacements of the nitro of group concerning a plane of a molecule. Calculations of frequency spectra were led on a method the Dyne.

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