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Atomically precise mechanosynthesis of carbon structures on hydrogenated Si(100) by inverted-mode STM

2026/05/26 by Megan Cowie, Chris Deimert, Ryan Groome +44 · 11 voices · 3 citations
#cond-mat.mtrl-sci

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Abstract

The ability to build atomically precise structures on surfaces with complete control over both atomic placement and chemical bonding remains a central challenge in nanoscale fabrication. Here, we demonstrate simultaneous spatial and chemical control over the mechanosynthetic fabrication of carbon structures. Using inverted-mode STM, C2 units are donated from surface-deposited molecules to pre-patterned reactive sites on a hydrogen-passivated Si(100) surface. We demonstrate single-site C2 donation, spatially patterned multi-site C2 donation, and the stepwise assembly of polyyne structures through successive C-C bond formation. Together, these results establish controlled mechanosynthetic donation as a foundational capability for programmable atomically precise fabrication.

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