Synthesis of the First Thorium-Containing Nitride Perovskite, TaThN3

1995/12/01 by Nathaniel E. Brese, F.J. DiSalvo, Francis J. DiSalvo · 6 citations
Chemistry · Materials Science · #Inorganic Chemistry and Materials #MXene and MAX Phase Materials #Ferroelectric and Piezoelectric Materials

paper · doi:10.1006/jssc.1995.1423

Abstract

TaThN3 can be prepared from a reaction of Ta2Th2O9 and Ca3N2 at 1100-1500°C or from a reaction of Ta3N5 and Th3N4 at 1400°C. This black polycrystalline material crystallizes in the perovskite structure type with a = 4.020(6) Å.

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• Orthorhombic nitride perovskite CeTaN3-δ with switchable and robust ferroelectric polarization
• Predicting the strain-mediated topological phase transition in 3D cubic ThTaN 3 . [europepmc]
• High-Throughput Selection and Experimental Realization of Two New Ce-Based Nitride Perovskites: CeMoN 3 and CeWN 3 . [europepmc]
• Accessible chemical space for metal nitride perovskites. [europepmc]
• Predicting band gaps of ABN 3 perovskites: an account from machine learning and first-principle DFT studies. [europepmc]
• Theoretical and data-driven approaches to semiconductors and dielectrics: from prediction to experiment. [europepmc]

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