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Microscopic Theory of a Fluctuation-Induced Dynamical Crossover in Supercooled Liquids

2025/12/15 by Laudicina, Corentin C. L., Janssen, Liesbeth M. C., Szamel, Grzegorz
#Chemical Physics (physics.chem-ph) #Disordered Systems and Neural Networks (cond-mat.dis-nn) #FOS: Physical sciences #Soft Condensed Matter (cond-mat.soft) #Statistical Mechanics (cond-mat.stat-mech)

paper · doi:10.48550/arxiv.2512.13082

Abstract

Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing discrepancy by incorporating critical dynamical fluctuations into a microscopic mode-coupling framework. We show that these fluctuations round off the mean-field singularity and restore ergodicity at all finite densities (or temperatures) without invoking activated dynamics or facilitation. The resulting effective theory describes the order parameter as a stochastic process with self-induced, annealed disorder, determined self-consistently at the mean-field level. In the β-relaxation regime it reduces to stochastic beta-relaxation theory, thereby unifying mode-coupling and replica-based approaches beyond mean-field. All parameters of the stochastic β-relaxation theory are fixed by the static structure, enabling parameter-free predictions that extend mean-field theory into finite dimensions.

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