Determination of the contribution of pair, triplet, and higher-order multiplet interactions to the excess free energy of mixing in mixed electrolyte solutions

1985/01/01 by Leslie Leifer, Rodney J. Wigent
Physics and Astronomy · Chemistry · Chemical Engineering · #Spectroscopy and Quantum Chemical Studies #Electrochemical Analysis and Applications #Chemical and Physical Properties in Aqueous Solutions

paper · doi:10.1021/j100248a013

Abstract

Methods have been developed to determine and separate contributions to the excess free energy of mixing due to interactions of pairs, triplets, and higher-order multiplets in mixed electrolyte systems. This method also indicates how to choose the proper combination of Scatchard bAB parameters to fit the experimental mixed electrolyte osmotic or activity coefficient data based on the type of interactions occurring in the solution. © 1985 American Chemical Society.

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