2007/12/12 by Kwan‐Nang Pang, K.-N. Pang, Mei‐Fu Zhou +7 · 231 citations
Chemistry · Earth and Planetary Sciences · #Chemistry #Fractionation #Geochemistry #Geological and Geochemical Analysis #Geology #High-pressure geophysics and materials #Intrusion #Large igneous province #Layered intrusion #Mafic #Magma #Magma chamber #Magmatism #Materials science #Metallurgy #Mineral #Mineralogy #Oxide #Volcano #earthquake and tectonic studies
paper · pdf · doi:10.1093/petrology/egm082
published in Journal of Petrology 49(2), 295-313 (Oxford University Press)
openalex publication_date 2007/12/12 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/26
Economic concentrations of FeTi oxides occur as massive, conform-able lenses or layers in the lower part of the Panzhihua intrusion, Emeishan Large Igneous Province, SW China. Mineral chemistry, textures and QUILF equilibria indicate that oxides in rocks of the intrusion were subjected to extensive subsolidus re-equilibration and exsolution. The primary oxide, reconstructed from compositions of titanomagnetite in the ores and associated intergrowths, is an alumi-nous titanomagnetite (Usp40) with 40 wt % FeO, 34 wt % Fe2O3, 165 wt % TiO2, 53 wt % Al2O3, 35 wt %MgO and 05 wt % MnO. This composition is similar to the bulk composition of the oxide ore, as inferred from whole-rock data.This similarity strongly suggests that the ores formed from accumulation of titanomagnetite crystals, not from immiscible oxide melt as proposed in earlier studies. The occurrence of oxide ores in the lower parts of the Panzhihua intrusion is best explained by settling and sorting of dense titanomag-netite in the ferrogabbroic parental magma.This magma must have crystallized FeTi oxides relatively early and abundantly, and is likely to have been enriched in Fe and Ti but poor in SiO2. These features are consistent with fractionation of mantle-derived melts under relatively high pressures (10 kbar), followed by emplacement of the residual magma at 5 kbar. This study provides definitive field and geochemical evidence that FeTi oxide ores can form by accumulation in ferrogabbro. We suggest that many other massive FeTi oxide deposits may have formed in a similar fashion and that high concentrations of phosphorus or carbon, or periodic fluctua-tion of fO2 in the magma, are of secondary importance in ore formation. KEY WORDS: ELIP; FeTi oxide ore; layered intrusion; Panzhihua; QUILF