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Highly Anisotropic Organometal Halide Perovskite Nanowalls Grown by Glancing‐Angle Deposition

2021/09/15 by Javier Castillo‐Seoane, Javier Castillo-Seoane, Lidia Contreras‐Bernal +32 · 1 citation
Chemistry · Engineering · Materials Science · #Chalcogenide Semiconductor Thin Films #Chemistry #Fabrication #Materials science #Nanorod #Nanotechnology #Optics #Optoelectronics #Perovskite (structure) #Perovskite Materials and Applications #Photoluminescence #Photovoltaic system #Photovoltaics #Physics #Polarization (electrochemistry) #Quantum Dots Synthesis And Properties

paper · pdf · doi:10.1002/adma.202107739

openalex publication_date 2022/01/25 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01

Abstract

Polarizers are ubiquitous components in current optoelectronic devices as displays or photographic cameras. Yet, control over light polarization is an unsolved challenge, since the main drawback of the existing display technologies is the significant optical losses. In such a context, organometal halide perovskites (OMHP) can play a decisive role given their flexible synthesis with tunable optical properties such as bandgap and photoluminescence, and excellent light emission with a low non-radiative recombination rate. Therefore, along with their outstanding electrical properties have elevated hybrid perovskites as the material of choice in photovoltaics and optoelectronics. Among the different OMHP nanostructures, nanowires and nanorods have lately arisen as key players in the control of light polarization for lighting or detector applications. Herein, the fabrication of highly aligned and anisotropic methylammonium lead iodide perovskite nanowalls by glancing-angle deposition, which is compatible with most substrates, is presented. Their high alignment degree provides the samples with anisotropic optical properties such as light absorption and photoluminescence. Furthermore, their implementation in photovoltaic devices provides them with a polarization-sensitive response. This facile vacuum-based approach embodies a milestone in the development of last-generation polarization-sensitive perovskite-based optoelectronic devices such as lighting appliances or self-powered photodetectors.

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