Facile Os-Os bond cleavage in the reactions of [Os3(CO)10(NCMe)2] and [Os3(CO)10(μ-H)2] with tetramethylthiuram disulfide (tmtd): Syntheses and crystal structures of new polynuclear osmium carbonyl complexes containing a dimethyldithiocarbamate ligand(s)

2020/01/24 by Nikhil C. Bhoumik, Tapan K. Saha, Tapan Saha +4 · 16 citations
Chemistry · Medicine · #Bond cleavage #Catalysis #Chelation #Chemistry #Crystal structure #Crystallography #Inorganic chemistry #Ligand (biochemistry) #Medicinal chemistry #Metal complexes synthesis and properties #Organic chemistry #Organometallic Complex Synthesis and Catalysis #Organometallic Compounds Synthesis and Characterization #Osmium #Ruthenium #Stereochemistry #Yield (engineering)

paper · doi:10.1016/j.jorganchem.2020.121133

published in Journal of Organometallic Chemistry 911, 121133 (Elsevier BV)

openalex publication_date 2020/01/24 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/26

Citations

• Intermolecular interactions from a natural bond orbital, donor-acceptor viewpoint
• OLEX2: a complete structure solution, refinement and analysis program

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