Tri and hexaosmium clusters bearing saccharinate and diphosphine ligands: Synthesis, structure and fluxionality

2024/05/31 by Md. Sohag Hasan, Md. Mahbub Alam, Mir Khaleda Parvin +4 · 8 citations
Chemistry · Materials Science · #Asymmetric Hydrogenation and Catalysis #Bearing (navigation) #Chemistry #Nanocluster Synthesis and Applications #Organometallic Complex Synthesis and Catalysis #Stereochemistry

paper · doi:10.1016/j.jorganchem.2024.123212

published in Journal of Organometallic Chemistry 1015, 123212 (Elsevier BV)

openalex publication_date 2024/05/31 · openalex created_date 2025/10/10 · openalex updated_date 2026/07/26

Citations

• Oxidative-addition of the N–H bond of saccharin (sacH) to a triosmium centre: Synthesis, structure and reactivity of Os3(CO)10(μ-H)(μ-sac)
• OLEX2: a complete structure solution, refinement and analysis program
• Reactions of [HOs3(CO)10(µ-L)] (L = saccharinate, thiosaccharinate) with Ph3SnH and Ph3GeH

Cited by

• Reactivity studies of saccharin at a diphosphine-stabilized low-valent triruthenium center to show a new, simple but elusive coordination mode of saccharinate ligand