Suzuki–Miyaura Cross-Coupling of Potassium Trifluoro(N-methylheteroaryl)borates with Aryl and Heteroaryl Halides

2013/06/25 by Gary A. Molander, DaWeon Ryu, Mona Hosseini-Sarvari +3 · 4 citations
Chemistry · Pharmacology, Toxicology and Pharmaceutics · #Catalytic Cross-Coupling Reactions #Fluorine in Organic Chemistry #Catalytic C–H Functionalization Methods

paper · doi:10.1021/jo4009589

Abstract

The synthesis of potassium trifluoro(N-methylheteroaryl)borates and their use in cross-coupling reactions with various aryl and heteroaryl halides to construct N-methyl heteroaryl-substituted aromatic and heteroaromatic compounds are reported.

Citations

• Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions
• Scope of Aminomethylations via Suzuki−Miyaura Cross-Coupling of Organotrifluoroborates

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• Suzuki–Miyaura (hetero-)aryl cross-coupling: recent findings and recommendations
• Organotrifluoroborates: Another Branch of the Mighty Oak
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