Palladium-Catalyzed Preparation of Silyl Enolates from α,β-Unsaturated Ketones or Cyclopropyl Ketones with Hydrosilanes

2009/09/18 by Yuto Sumida, Hideki Yorimitsu, Koichiro Oshima
Chemistry · #Catalytic Cross-Coupling Reactions #Organoboron and organosilicon chemistry #Cyclopropane Reaction Mechanisms

paper · doi:10.1021/jo901513v

Abstract

Alpha,beta-unsaturated ketones and cyclopropyl ketones undergo palladium-catalyzed hydrosilylation with hydrosilanes to yield (Z)-silyl enolates.

Citations

• Hydrosilylation of enones: platinum divinyltetramethyldisiloxane complex in the preparation of triisopropylsilyl and triphenylsilyl enol ethers

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