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Location of Cerium in Coal-Combustion Fly Ashes

2024/10/11 by James C. Hower, Hower, James C., John Groppo +3
Earth and Planetary Sciences · Engineering · #Coal and Its By-products #FOS: Environmental engineering #Geochemistry and Elemental Analysis #Recycling and utilization of industrial and municipal waste in materials production

paper · doi:10.4177/ccgp-d-13-00007.1

openalex created_date 2016/06/24 · openalex publication_date 2024/10/11 · openalex updated_date 2026/08/01

Abstract

Given the worldwide demand for rare earth elements (REEs) in modern electronics, all potential sources of the REEs should be investigated. Coal-combustion fly ash represents a potential source of REEs. Fly ashes, derived from the combustion of coals from Kentucky in the United States and Jungar in China, were examined by wavelength-dispersive spectrometry electron microprobe analysis of epoxy-bound polished pellets. From previous studies, it was known that the REEs did not show any enrichment relative to flue gas temperature at the point of collection or to the particle size, that is, external surface area, of the particles. Cerium, the most abundant of the REEs in these fly ashes, was used as a proxy for the entire suite of REEs. For fly ashes from both sources, Ce is disbursed throughout the glassy fly ash particles. For fly ash processing with respect to the recovery of REEs, this implies that the entire particle must be leached to maximize the element recovery.

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