2018/12/31 by Ali Moeed Tirmzi, Jeffrey A. Christians, Ryan P. Dwyer +2 · 13 citations
Engineering · Materials Science · Physics and Astronomy · #Alloy #Chalcogenide Semiconductor Thin Films #Chemical engineering #Dynamics (music) #Geology #Materials science #Metallurgy #Optoelectronics #Perovskite (structure) #Perovskite Materials and Applications #Photoconductivity #Physics #Solid-state spectroscopy and crystallography #Substrate (aquarium) #cond-mat.mtrl-sci #physics.app-ph
paper · pdf · open access · doi:10.1021/acs.jpcc.8b11783
published in The Journal of Physical Chemistry C 123(6), 3402-3415 (American Chemical Society)
arxiv created 2019/01/16 · openalex publication_date 2019/01/17 · arxiv updated 2019/01/18 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/05
Films of (FA0.79MA0.16Cs0.05)0.97Pb(I0.84Br0.16)2.97 were grown over TiO2, SnO2, indium tin oxide (ITO), and NiO. Film conductivity was interrogated by measuring the in-phase and out-of-phase forces acting between the film and a charged microcantilever. We followed the films’ conductivity versus time, frequency, light intensity, and temperature (233−312 K). Perovskite conductivity was high and light-independent over ITO and NiO. Over TiO2 and SnO2, the conductivity was low in the dark,increased with light intensity, and persisted for 10’s of seconds after the light was removed. At an elevated temperature over TiO2, the rate of conductivity recovery in the dark showed an activated temperature dependence (Ea= 0.58eV). Surprisingly, the light-induced conductivity over TiO2 and SnO2 relaxed essentially instantaneously at a low temperature. We use a transmission-line model for mixed ionic−electronic conductors to show that the measurements presented are sensitive to the sum of electronic and ionic conductivities. We rationalize the seemingly incongruous observations using the idea that holes, introduced either by equilibration with the substrate or via optical irradiation, create iodide vacancies.