2025/10/09 by Yingchen Peng, Peng, Yingchen, Yanan Ge +12
#cond-mat.mtrl-sci
paper · pdf · doi:10.48550/arxiv.2510.07996
Layered van der Waals (vdW) magnetic semiconductors open a new avenue for exploring intertwined excitonic and magnetic phenomena. Here, we investigate this interplay in the vdW antiferromagnet MnPS3, uncovering an exceptionally long exciton lifetime (~100 μs) below the Néel temperature (TN). We demonstrate that the exciton lifetime is governed by phonon-assisted nonradiative recombination and thus exhibits a strong temperature dependence. In contrast, the exciton radiative recombination shows a distinct temperature dependence that is sensitive to magnetic order. Below TN, the temperature dependence of the radiative recombination rate is consistent with a magnon-assisted emission pathway, while above TN it reflects the combined effects of short-range spin correlations and phonons. These findings not only establish MnPS3 as a compelling candidate for excitonic devices due to its long-lifetime and correlation with magnetic orders but also provide crucial insights into the interplay between excitons, spins, and lattice in vdW magnetic semiconductors.