Origins of 1,2- and 1,3-stereoselectivity in dicobaltoctacarbonyl alkene-alkyne cyclizations for the synthesis of substituted bicyclo[3.3.0]octenones.

1985/01/01 by Philip Magnus, Lawrence M. Principe · 3 citations
Chemistry · #Alkene #Alkyne #Bicyclic molecule #Catalysis #Catalytic Alkyne Reactions #Chemistry #Organic chemistry #Oxidative Organic Chemistry Reactions #Stereochemistry #Stereoselectivity #Synthetic Organic Chemistry Methods

paper · doi:10.1016/s0040-4039(00)94968-2

crossref issued 1985/01/01 · crossref published 1985/01/01 · crossref published-print 1985/01/01 · openalex publication_date 1985/01/01 · crossref created 2002/07/25 · crossref deposited 2019/04/20 · openalex created_date 2025/10/10 · crossref indexed 2026/04/04 · openalex updated_date 2026/06/26

Citations

• A simple organocobalt mediated synthesis of substituted 3-oxabicyclo[3.3.0]oct-6-en-7-ones
• Organocobalt complexes. Part II. Reaction of acetylenehexacarbonyldicobalt complexes, (R1C2R2)Co2(CO)6, with norbornene and its derivatives

Cited by

• The Pauson–Khand reaction, a powerful synthetic tool for the synthesis of complex molecules
• The P auson– K hand Cycloaddition Reaction for Synthesis of Cyclopentenones
• Pauson–Khand reaction [wikipedia]