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Chemical and Technical Aspects of Propene Oxide Production via Hydrogen Peroxide (HPPO Process)

2012/12/24 by Vincenzo Russo, Riccardo Tesser, E. Santacesaria +1 · 1 citation
Materials Science · Chemical Engineering · Chemistry · #Catalytic Processes in Materials Science #Catalysis and Oxidation Reactions #Zeolite Catalysis and Synthesis #Propene #Oxidizing agent #Catalysis #Hydrogen peroxide #Oxide #Chemistry #Process (computing) #Propylene oxide #Titanium oxide #Materials science #Organic chemistry #Computer science

paper · doi:10.1021/ie3023862

openalex publication_date 2012/12/24 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/01

Abstract

Propene oxide is a very important chemical whose production technology has changed a lot during the last 30 years. Nowadays, the most promising technology is the HPPO process in which the propene oxide is produced by oxidizing propene with hydrogen peroxide, via titanium silicalite-1 (TS-1) catalysis. Even if this technology has been patented in the early 1980s and some chemical plants are already in production, only few papers have been published until now dealing with the catalytic and kinetic aspects of the process. In this paper, the state of the art of the scientific knowledge and technical aspects related to propene oxide synthesis in the presence of TS-1 catalyst have been reviewed.

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