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High-Temperature Superconductivity in Hydrides: Experimental Evidence and Details

2022/03/25 by M. I. Eremets, Vasily S. Minkov, А. П. Дроздов +9 · 2 citations
Physics and Astronomy · Engineering · #Superconductivity in MgB2 and Alloys #Physics of Superconductivity and Magnetism #Superconducting Materials and Applications #Superconductivity #Materials science #Condensed matter physics #High-temperature superconductivity #Room-temperature superconductor #Physics

paper · pdf · doi:10.1007/s10948-022-06148-1

openalex publication_date 2022/03/25 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/05

Abstract

Abstract Since the discovery of superconductivity at ~ 200 K in H 3 S [1], similar or higher transition temperatures, T c s, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved by different methods, including electrical resistance, magnetic susceptibility, optical infrared, and nuclear resonant scattering measurements. The crystal structures of superconducting phases were determined by X-ray diffraction. Numerous electrical transport measurements demonstrate the typical behavior of a conventional phonon-mediated superconductor: zero resistance below T c , shift of T c to lower temperatures under external magnetic fields, and pronounced isotope effect. Remarkably, the results are in good agreement with the theoretical predictions, which describe superconductivity in hydrides within the framework of the conventional BCS theory. However, despite this acknowledgement, experimental evidences for the superconducting state in these compounds have recently been treated with criticism [3–7], which apparently stems from misunderstanding and misinterpretation of complicated experiments performed under very high pressures. Here, we describe in greater detail the experiments revealing high-temperature superconductivity in hydrides under high pressures. We show that the arguments against superconductivity [3–7] can be either refuted or explained. The experiments on the high-temperature superconductivity in hydrides clearly contradict the theory of hole superconductivity [8] and eliminate it [3].

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