2016/03/23 by Yue Zhang, Ethan Glor, Mu Li +5
Physics and Astronomy · #cond-mat.soft
paper · pdf · doi:10.1063/1.4962734
5 pages, 4 figures
arxiv created 2016/03/23 · arxiv updated 2016/10/12
Physical vapor deposition (PVD) is widely used in manufacturing ultra-thin layers of amorphous organic solids. Here, we demonstrate that these films exhibit a sharp transition from glassy solid to liquid-like behavior with thickness below 30 nm. This liquid-like behavior persists even at temperatures well below the glass transition temperature, Tg. The enhanced dynamics in these films can produce large scale morphological features during PVD and lead to a dewetting instability in films held at temperatures as low as Tg-35 K. We measure the effective viscosity of organic glass films by monitoring the dewetting kinetics. These measurements combined with cooling rate-dependent Tg measurements show that the apparent activation barrier for rearrangement decreases sharply in films thinner than 30 nm. These observations suggest long-range facilitation of dynamics induced by the free surface, with dramatic effects on the properties of nano-scale amorphous materials.