1975/01/01 by Richard A. Andersen, G. E. Coates · 1 citation
Chemistry · Pharmacology, Toxicology and Pharmaceutics · #Beryllium #Chemistry #Crystallography #Ether #Fluorine in Organic Chemistry #Inorganic Fluorides and Related Compounds #Inorganic chemistry #Medicinal chemistry #Melting point #Monomer #Organic chemistry #Polymer #Polymer chemistry #Pyridine #Synthesis and characterization of novel inorganic/organometallic compounds
paper · doi:10.1039/dt9750001244
openalex publication_date 1975/01/01 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/11
Bis(nonafluoro-t-butoxy)beryllium, [[(CF3)3CO]2Be2], prepared from (CF3)3COH and Et2Be, is dimeric in C6F6 and is thermally stable well above its melting point. The abnormally weak bridge Be–O bond results in fission t dlethyl ether yielding monomeric [(CF3)3CO2Be]·OEt2. Complexes [Be(CF3)3CO2L2](L = ammonia or pyridine) are also described.