Teaching Thermodynamics with the Quantum Volume

2020/01/27 by Ted H. Yu · 2 citations
Physics and Astronomy · #Advanced Thermodynamics and Statistical Mechanics #Statistical Mechanics and Entropy #Quantum Mechanics and Applications

paper · doi:10.1021/acs.jchemed.9b00742

Abstract

The author introduces the concept of the quantum volume into thermodynamics teaching. A new derivation of the basic part of the Sackur–Tetrode equation uses the microcanonical ensemble instead of the math-heavy canonical ensemble. Entropy diagrams, based on the binomial distribution, visualize the ratio between the quantum volume and system volume.

Citations

• On the equilibrium of heterogeneous substances

Cited by

• Lattice Models in Molecular Thermodynamics: Merging the Configurational and Translational Entropies. [europepmc]
• A Pedagogical Reinforcement of the Ideal (Hard Sphere) Gas Using a Lattice Model: From Quantized Volume to Mechanical Equilibrium. [europepmc]

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