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New Intercalation Superconductor Lix(C6H16N2)yFe2−zSe2 with a Very Large Interlayer-Spacing and Tc = 38 K

2014/10/09 by Shohei Hosono, S. Hosono, T. Noji +9 · 65 citations
Materials Science · Physics and Astronomy · #Electrical resistivity and conductivity #Intercalation (chemistry) #Iron-based superconductors research #Lithium (medication) #Magnetic susceptibility #Rare-earth and actinide compounds #Superconductivity #Superconductivity in MgB2 and Alloys #Transition temperature #cond-mat.supr-con

paper · pdf · doi:10.7566/jpsj.83.113704

published in Journal of the Physical Society of Japan 83(11), 113704 (Physical Society of Japan) · 10 pages, 5 figures

openalex publication_date 2014/10/09 · arxiv created 2015/10/29 · arxiv updated 2016/01/14 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

A new iron-based superconductor, Lix(C6H16N2)yFe2-zSe2, with Tc = 38 K has successfully been synthesized via the intercalation of lithium and hexamethylenediamine into FeSe. The superconducting transition has been confirmed not only by magnetic susceptibility measurements but also by electrical resistivity ones. The interlayer spacing, namely, the dicstance between neighboring Fe layers, d, is 16.225(5) \mathringA, which is the largest among those of FeSe-based intercalation compounds. It has been found that the dependence of Tc on d in FeSe-based intercalation superconductors appears domic.

Citations