1999/03/23 by Helen C. Aspinall, J.L.M. Dwyer, Nick Greeves +1 · 1 citation
Chemistry · #Alkyl #Anhydrous #Asymmetric Hydrogenation and Catalysis #Catalysis #Chemistry #Coordination Chemistry and Organometallics #Enantioselective synthesis #Ion #Lanthanide #Lithium (medication) #Medicinal chemistry #Organic chemistry #Organophosphorus compounds synthesis #Reagent #Tris
paper · doi:10.1021/om981011s
openalex publication_date 1999/03/23 · openalex created_date 2025/10/10 · openalex updated_date 2026/06/26
Anhydrous lithium lanthanide binaphtholates have been prepared by reaction of lanthanide tris(silylamides) with 3 equiv of LiHbinol. Li 3 [Y( R -binol) 3 ]·6THF has been characterized by single-crystal X-ray diffraction, and Li 3 [La( S -binol) 3 ]·6THF has been shown to be an effective reagent for the enantioselective addition of MeLi to a range of aldehydes.