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Synthesis by molten salt method of the AFeO3 system (A=La, Gd) and its structural, vibrational and internal hyperfine magnetic field characterization

2014/02/17 by M. Romero, R. Gómez, V. Marquina +4 · 86 citations
Chemistry · Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Analytical Chemistry (journal) #Atomic physics #Chemistry #Crystal structure #Crystallite #Crystallography #Electronic and Structural Properties of Oxides #Hyperfine structure #Inorganic chemistry #Ion #Ionic bonding #Magnetic and transport properties of perovskites and related materials #Materials science #Molten salt #Mössbauer spectroscopy #Nuclear magnetic resonance #Optics #Organic chemistry #Physics #Raman spectroscopy #Rietveld refinement #Spectroscopy #cond-mat.mtrl-sci

paper · pdf · doi:10.1016/j.physb.2014.03.024

published in Physica B Condensed Matter 443, 90-94 (Elsevier BV) · 10 figures

arxiv created 2014/02/17 · openalex publication_date 2014/03/22 · arxiv updated 2015/06/18 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

Polycrystalline samples of LaFeO3 and GdFeO3 were synthesized by the molten salt method. Some properties and the quality of the resulting compounds were investigated. The crystal structure and purity of the samples was determined through X-ray diffraction and Rietveld analysis. The vibrational properties were characterized by Raman and IR spectroscopy. Mössbauer spectroscopy was used to determine the ionic state of the Fe ions and the internal hyperfine magnetic fields Considerable reduction of the heat treatment (temperature and time) for the reaction to take place was achieved without detriment of the quality of the compounds.

Citations