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Quasi-one-dimensional antiferromagnetism and multiferroicity in CuCrO<mml:mrow/>4

2011/06/03 by J. M. Law, Joseph M. Law, P. Reuvekamp +9
Chemistry · Materials Science · Physics and Astronomy · #Advanced Condensed Matter Physics #Antiferromagnetism #Chemistry #Condensed matter physics #Crystallography #Dielectric #Electron paramagnetic resonance #Magnetic susceptibility #Materials science #Multiferroics and related materials #Nuclear magnetic resonance #Physics #Physics of Superconductivity and Magnetism #Quantum mechanics #Specific heat #cond-mat.mtrl-sci #cond-mat.str-el

paper · pdf · doi:10.1103/physrevb.84.014426

9 pages, 8 figures, submitted to PRB

arxiv created 2011/06/03 · openalex publication_date 2011/07/28 · arxiv updated 2015/05/28 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

The bulk magnetic properties of the new quasi-one-dimensional Heisenberg antiferromagnet, CuCrO4, were characterized by magnetic susceptibility, heat capacity, optical spectroscopy, electron paramagnetic resonance and dielectric capacitance measurements, and density functional evaluations of the intrachain and interchain spin-exchange interactions. We found type-II multiferroicity below the N'eel temperature of 8.2(5) K, arising from competing antiferromagnetic nearest-neighbor (Jnn) and next-nearest-neighbor (Jnnn) intrachain spin-exchange interactions. Experimental and theoretical results indicate that the ratio Jnn/Jnnn is close to 2, putting CuCrO4 in the vicinity of the Majumdar-Ghosh point.

Citations