2014/11/21 by Y. Li, Z. Y. Wei, Zhiyang Wei +7 · 1 citation
Chemistry · Materials Science · Physics and Astronomy · #Chemical physics #Chemistry #Condensed matter physics #Crystallography #Doping #Electronic structure #Engineering physics #Heusler alloys: electronic and magnetic properties #Magnetic Properties of Alloys #Magnetic and transport properties of perovskites and related materials #Materials science #Nanotechnology #Optoelectronics #Physics #cond-mat.mtrl-sci
paper · pdf · doi:10.1063/1.4916107
published as J. Appl. Phys. 117, 17C117 (2015) · 13 pages, 5 figs. Accepted by JAP
arxiv created 2014/11/21 · openalex publication_date 2015/03/24 · arxiv updated 2015/04/17 · openalex created_date 2025/10/10 · openalex updated_date 2026/08/05
The structural transitions, magnetic properties, and electronic structures of Co(Fe)-doped MnNiSi compounds are investigated by x-ray powder diffraction, differential scanning calorimetry (DSC), magnetic measurements, and first-principles calculations. Results indicate that all samples undergo a martensitic transition from the Ni2In-type parent phase to TiNiSi-type orthorhombic phase at high temperatures. The substitution of Co(Fe) for Mn in Mn1−xCoxNiSi (x = 0.2, 0.3, and 0.4) and Mn1−yFeyNiSi (y = 0.26, 0.30, 0.36, 0.46, and 0.55) samples decreases the structural transition temperature and Curie temperature of martensite. The martensite phases show a typical ferromagnetic behavior with saturation field being basically unchanged with increasing Co(Fe) content, while the saturation magnetization shows a decreasing tendency. The theoretically calculated moments are in good agreement with the experimentally measured results. The orbital hybridizations between different 3d elements are analyzed from the distribution of density of states.