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Emergence of ferroelectricity and spin-valley properties in two-dimensional honeycomb binary compounds

2014/12/30 by Domenico Di Sante, Alessandro Stroppa, Paolo Barone +3 · 155 citations
Chemistry · Engineering · Materials Science · Mathematics · Physics and Astronomy · #2D Materials and Applications #Binary number #Bistability #Chemistry #Condensed matter physics #Dielectric #Dipole #Electric field #Ferroelectric and Negative Capacitance Devices #Ferroelectricity #Honeycomb #Materials science #Mathematics #Multiferroics and related materials #Optoelectronics #Physics #Polarization (electrochemistry) #Quantum mechanics #Spin (aerodynamics) #cond-mat.mes-hall #cond-mat.mtrl-sci

paper · pdf · doi:10.1103/physrevb.91.161401

published in Physical Review B 91(16) (American Physical Society)

arxiv created 2014/12/30 · openalex publication_date 2015/04/06 · arxiv updated 2015/04/16 · openalex created_date 2016/06/24 · openalex updated_date 2026/08/05

Abstract

First-principles calculations presented in this Rapid Communication suggest that a number of A\phantom\rule00exB binary honeycomb monolayers should be ferroelectric. Dipoles arise from the buckled structure, and the polarization reversal occurs via switching the structural buckling which can be triggered by an external electric field. The authors address the emerging valley-dependent properties arising from the ferroelectric bistability and explore the intimate link between ferroelectricity, spin-valley physics, and Rashba spin-splitting phenomena.

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